Journal
CHEMISTRY LETTERS
Volume 38, Issue 8, Pages 838-839Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.838
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- Ministry of Education, Culture, Sports, Science and Technology, Japan
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Ethanol was efficiently converted into n-butanol in the presence of a catalytic amount of [Ir(acac)(cod)], 1,7-octadiene, and EtONa. This method provides an efficient alternative approach to n-butanol which is conventionally manufactured by oxo process of propylene with H-2 and CO followed by hydrogenation of butyraldehyde.
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