Journal
CHEMISTRY LETTERS
Volume 38, Issue 7, Pages 702-703Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.702
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan [18002016]
- Nissan Science Foundation
- Grants-in-Aid for Scientific Research [18002016] Funding Source: KAKEN
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[Ru(tmtacn)(R(2)bpy)(OH2)](2+) (tmtacn = 1,4,7-trimethyl-1,4,7-triazacyclononane; R(2)bpy = 4,4'-disubstituted-2,2'-bipyridines, R = H, Me, and OMe) with tmtacn ligated in a facial fashion is found to be active as O-2-evolving catalysts. It is also found that the stronger electron-donating character of R(2)bpy gives rise to the higher O-2-evolving activity.
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