Journal
CHEMISTRY LETTERS
Volume 38, Issue 10, Pages 1006-1007Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.1006
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Funding
- JSPS [21390030]
- TOSOH F-TECH INC.
- Grants-in-Aid for Scientific Research [21390030] Funding Source: KAKEN
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The first enantioselective construction of nonadjacent 1,3-tertiary-quaternary stereocenters containing a trifluoromethylated carbon by cinchona alkaloid-catalyzed Michael addition of beta-ketoesters to 2-(trifluoromethyl)acrylate has been achived in high yields with high enantioselectivities up to 97% ee.
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