Journal
CHEMISTRY LETTERS
Volume 37, Issue 5, Pages 502-503Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.502
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The vanadium(V)(salalen) complex prepared in situ from the corresponding vanadium(IV) complex 4 under aerobic conditions was found to be an excellent catalyst for asymmetric transcyanation of aliphatic aldehydes with acetone cyanohydrin as the cyanide source, showing high enantioselectivity of 91-95% ee.
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