Journal
CHEMISTRY LETTERS
Volume 37, Issue 2, Pages 192-193Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.192
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Lipophilic, linear cobalt(II) triazole complex Co(1)(3)Cl-2 in chloroform shows sol-to-gel transition upon addition of long-chained alcohols. Binding of alcohol molecules induces coordination structure changes (octahedral, Oh to tetrahedral, T-d), which promotes aggregation of nanofibers and concomitant physical gelation. The surface of lipophilic, linear complexes provides binding sites for guest molecules, which is referred to as adaptive molecular clefts.
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