4.3 Article

An Efficient One-pot Three-component Reaction to Produce 1,4-Disubstituted-1,2,3-triazoles Catalyzed by a Dicopper-substituted Silicotungstate

Journal

CHEMISTRY LETTERS
Volume 37, Issue 12, Pages 1258-1259

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.1258

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan

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The dicopper-substituted gamma-Keggin silicotungstate with bis-mu-1-1-azido ligands TBA(4)H(2)[gamma-SiW10O36Cu2(mu-1,1-N-3)(2)] (TBA = tetrabutylammonium) could act as an effective homogeneous precatalyst for the one-pot synthesis of various kinds of 1,4-disubstituted-1,2,3-triazole derivatives from organic halides, NaN3, and alkynes.

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