Journal
CHEMISTRY LETTERS
Volume 37, Issue 12, Pages 1238-1239Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.1238
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan [18550116]
- Grants-in-Aid for Scientific Research [18550116] Funding Source: KAKEN
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This study describes the synthesis of a new compound: boronate ester-substituted cyclotricatechylene 1. The structure-directing property of the boronic acid-diol interactions is responsible for the shuttlecock-shaped structure of 1, which led to the gelation of several solvents. The distribution control of trigonal and tetrahedral boronate esters allows phase transition via chemical stimulus.
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