4.3 Article

Development of Chemical Stimuli-responsive Organogel Using Boronate Ester-substituted Cyclotricatechylene

Journal

CHEMISTRY LETTERS
Volume 37, Issue 12, Pages 1238-1239

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.1238

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan [18550116]
  2. Grants-in-Aid for Scientific Research [18550116] Funding Source: KAKEN

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This study describes the synthesis of a new compound: boronate ester-substituted cyclotricatechylene 1. The structure-directing property of the boronic acid-diol interactions is responsible for the shuttlecock-shaped structure of 1, which led to the gelation of several solvents. The distribution control of trigonal and tetrahedral boronate esters allows phase transition via chemical stimulus.

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