4.3 Article

Crystal structures and magnetic properties of [MnII(rac-pnH)(H2O)CrIII(CN)6]•H2O and its dehydrated form

Journal

CHEMISTRY LETTERS
Volume 37, Issue 6, Pages 586-587

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.586

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An irreversible single-crystal-to-single-crystal transformation is observed upon dehydration of [Mn-II(rac-pnH)(H2O)Cr-III(CN)(6)]center dot H2O. The virgin, dehydrated, and rehydrated phases are ferrimagnets with Curie temperature of 36, 70, and 36 K, respectively.

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