Journal
CHEMISTRY LETTERS
Volume 37, Issue 7, Pages 724-725Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.724
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A ruthenium-catalyzed 1,4-addition of organoboronic acids to alpha,beta-unsaturated ketones has been developed. The use of 2-(di-tert-butylphosphino)biphenyl as the ligand in combination with [RuCl2(p-cymene)](2) complex catalyzes these reactions to selectively give 1,4-adducts in good yield by effectively suppressing Heck-type and reduced products.
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