4.3 Article

Fluoride-ion-mediated Hydrolysis of Phosphoric Acid Esters, Amides, and Phosphorous Acid Esters Leading to Phosphorofluoridic, Phosphoramide Fluoridic, and Phosphonic Acid Monoester Salts

Journal

CHEMISTRY LETTERS
Volume 37, Issue 12, Pages 1198-1199

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.1198

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [20036020]
  2. Grants-in-Aid for Scientific Research [20036020] Funding Source: KAKEN

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Fluoride-ion-promoted hydrolysis of phosphoric acid esters and amides to give phosphorofluoridic and phosphoramide fluoridic acid monoester salts takes place upon treatment with a THF solution of TBAF, whereas a similar treatment of phosphorous acid esters generates phosphonic acid monoester salts selectively without introduction of fluorine.

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