Journal
CHEMISTRY & BIODIVERSITY
Volume 10, Issue 7, Pages 1193-1201Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cbdv.201300042
Keywords
Aspergillus niger; Fungi; Naphtho--pyrones; Malformin A(1); Cytotoxic activity
Funding
- National Natural Science Foundation of China [30925038, 81273383]
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Bioactivity-guided fractionation of the cytotoxic extract of Aspergillus niger, an endophytic fungus from the Chinese liverwort Heteroscyphus tener (Steph.) Schiffn., afforded five new naphtho--pyrones, rubrofusarin-6-O--D-ribofuranoside (1), (R)-10-(3-succinimidyl)-TMC-256A1 (2), asperpyrone E (3), isoaurasperone A (4), and isoaurasperone F (5), as well as four known ones, dianhydroaurasperone C (6), aurasperone D (7), asperpyrone D (8), and asperpyrone A (9), together with a cytotoxic cyclic pentapeptide, malformin A(1) (10). Their structures were determined by extensive spectroscopic analysis. The absolute configurations of dimeric naphtho--pyrones 3-9 were also determined by analysis of their respective CD spectra.
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