Journal
CHEMISTRY & BIODIVERSITY
Volume 6, Issue 1, Pages 71-78Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cbdv.200700416
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The mononuclear complex [Cu-II(phen)((L-Tyr)(H2O)] was synthesized and structurally characterized by elemental analysis, magnetic susceptibility, UV/VIS, IR, and EPR spectroscopy, and ESI mass spectrometry. The electronic and EPR spectral data suggest a square-pyramidal geometry around Cu-II. Absorption spectra, thermal denaturation, and fluorescence-spectroscopic studies were conducted to assess the interaction of the Cu-II complex with calf thymus DNA ((7 DNA). The intrinsic binding constant for CT DNA/complex(K-b=3750M (1))and Stern-Volmer quenching constant (K=0.39) were determined.
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