Journal
CHEMIE INGENIEUR TECHNIK
Volume 83, Issue 1-2, Pages 183-190Publisher
WILEY-BLACKWELL
DOI: 10.1002/cite.201000155
Keywords
Adsorption; Fixed bed; Gas separation; Hydrogen purification; Methane; Modeling
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Funding
- INNO-WATT [IW070135]
- CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico - Brazil)
- DAAD (Deutscher Akademischer Austausch Dienst - Germany)
- CarboTech AC GmbH
- CWK Chemiewerk Bad Kostritz GmbH
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This work provides a series of methane adsorption isotherms and breakthrough curves on one 5A zeolite and one activated carbon. Breakthrough curves of CH4 were obtained from dynamic column measurements at different temperature and pressure conditions for concentrations of 4.4-17.3 mol.-% in H-2/CH4 mixtures. A simple model was developed to simulate the curves using measured and calculated data inputs. The results show that the model predictions agree very well with the experiments.
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