Journal
CHEMICAL SOCIETY REVIEWS
Volume 47, Issue 22, Pages 8263-8306Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cs00370j
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Funding
- Charles University Centre of Advanced Materials (CUCAM) (OP VVV Excellent Research Teams) [02.1.01/0.0/0.0/15_003/0000417]
- Czech Science Foundation [P106/12/G015]
- European Union [604307]
- Spanish Ministry of Economy and Competitiveness through the CATPLASBIO project [CTQ2014-602209-R]
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Research activities and recent developments in the area of three-dimensional zeolites and their two-dimensional analogues are reviewed. Zeolites are the most important industrial heterogeneous catalysts with numerous applications. However, they suffer from limited pore sizes not allowing penetration of sterically demanding molecules to their channel systems and to active sites. We briefly highlight here the synthesis, properties and catalytic potential of three-dimensional zeolites followed by a discussion of hierarchical zeolites combining micro- and mesoporosity. The final part is devoted to two-dimensional analogues developed recently. Novel bottom-up and top-down synthetic approaches for two-dimensional zeolites, their properties, and catalytic performances are thoroughly discussed in this review.
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