4.8 Review

[4+2] and [4+3] catalytic cycloadditions of allenes

Journal

CHEMICAL SOCIETY REVIEWS
Volume 43, Issue 9, Pages 2904-2915

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cs00024b

Keywords

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Funding

  1. Spanish MINECO [SAF2010-20822-C01/02, CSD2007-00006]
  2. ERDF
  3. Xunta de Galicia [GRC2010/12, GR2013-041, INCITE09 209084PR]

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This feature review describes the development of catalytic [4+2] and [4+3] cycloadditions of allenes, as efficient and practical methodologies for assembling six and seven-membered cyclic systems. The different methodologies have been classified depending on the type of key reactive intermediate that was proposed in the catalytic cycle.

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