Journal
CHEMICAL SOCIETY REVIEWS
Volume 43, Issue 2, Pages 707-733Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cs60189g
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- Department of Science and Technology
- Council of Scientific and Industrial Research, New Delhi
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Half-sandwich arene ruthenium complexes exhibit versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations. This review mainly focuses on the chemistry of piano-stool ruthenium complexes with special emphasis on the achiral or chiral-at-ruthenium center. Also, it deals with the synthesis, nomenclature and stereochemistry of arene ruthenium complexes along with mechanistic insights into the epimerization reactions and their applications in catalytic organic transformations with some selected examples.
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