Journal
CHEMICAL SOCIETY REVIEWS
Volume 43, Issue 15, Pages 5245-5256Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cs00004h
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Funding
- National Natural Science Foundation of China [21372114, 21172106, 21074054]
- National Basic Research Program of China [2010CB923303]
- Research Fund for the Doctoral Program of Higher Education of China [20120091110010]
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C-H bonds are ubiquitous in organic molecules. Homogenous gold-catalyzed direct functionalization of unsaturated C-H bonds has emerged as a powerful method in our synthetic toolbox. However, C-sp3-H bonds have larger dissociation energy and lower proton acidity, and thus the efficient and exquisitely selective cleavage of this kind of chemical bonds for the formation of new carbon-carbon and carbon-heteroatom bonds is still a great challenge. In this tutorial review, we will highlight the recent achievements of gold-catalyzed oxidative and redox-neutral C-sp3-H bond functionalization, which opens new avenues for economical and sustainable construction of fine chemicals.
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