Journal
CHEMICAL SOCIETY REVIEWS
Volume 43, Issue 9, Pages 2941-2955Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cs60441a
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Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allenes which are based on computational studies, labelling studies, the detection of intermediates, chirality transfer and diastereoselective product formation.
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