Journal
CHEMICAL SOCIETY REVIEWS
Volume 42, Issue 3, Pages 1121-1146Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cs35397k
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Funding
- F.W.O. (Fund for Scientific Research Flanders (Belgium)
- University of Leuven (KU Leuven)
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In recent years, reaction of inexpensive and abundantly available alcohols (C-OH) with unactivated nucleophilic coupling partners (C-H), leading to the construction of the C-C bond, has emerged as one of the vital strategies since it is an atom-economical and environmentally benign approach with water as the by-product. Various transition metal-catalyzed or metal-free approaches for the direct dehydrative coupling employing the C-OH bond (including in situ activation) have recently been devised. This review article aims to highlight advances in such waste-free C-C bond forming dehydrative strategies.
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