Journal
CHEMICAL SOCIETY REVIEWS
Volume 42, Issue 21, Pages 8360-8375Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cs60162e
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Funding
- National Natural Science Foundation of China [21231007, 21172274, 21171177, 21121061, J1103305]
- National High-Tech Research and Development Programme of China (863 Program) [2012AA020305]
- Ministry of Education of China [20100171110013, 313058]
- Guangdong Provincial Natural Science Foundation [9351027501000003]
- Fundamental Research Funds for the Central Universities
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Non-covalent interactions in the second coordination sphere of metalloenzymes play a significant role in determining activity and selectivity. The importance of these interactions is reflected in the increasing number of reports on model complexes with a functional second coordination sphere. These hybrid mimics were developed according to the strategies of modification with functional groups, combination with supramolecular hosts and coupling with polymers, to shed light on the role of non-covalent interactions in metalloenzyme catalysis. This review provides an overview of recent progress in this area. An introduction to native metalloenzymes with an emphasis on the second coordination sphere is also given.
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