Journal
CHEMICAL SOCIETY REVIEWS
Volume 41, Issue 9, Pages 3464-3484Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cs15323h
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Funding
- National Basic Research Program of China (973 Program) [2009CB825300]
- National Science Foundation of China [20872003, 21172006]
- Peking University
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Copper salts have been developed as versatile catalysts for oxidative coupling reactions in organic synthesis. During these processes, Cu-catalysts are often proposed to serve as a one-electron oxidant to promote the single-electron transfer process. Recently, the transition-metal catalyzed direct dehydrogenative transformation has attracted considerable attention. This tutorial review summarizes the recent advances in the copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process achieving C-C, C-N, C-O, C-halogen atoms, C-P, and N-N bond formation.
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