4.8 Review

Strained small rings in gold-catalyzed rapid chemical transformations

Journal

CHEMICAL SOCIETY REVIEWS
Volume 41, Issue 8, Pages 3318-3339

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cs15295a

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Funding

  1. Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
  2. National Basic Research Program of China (973) [2009CB825300]
  3. National Natural Science Foundation of China [21072206, 20472096, 20872162, 20672127, 20821002, 20732008]

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Gold-catalyzed reactions, which have been widely explored over the past several years, are powerful tools in organic synthesis to access complex molecular frameworks, and some corresponding excellent reviews have been reported. However, little attention has been paid to summarize the reactions of strained small-ring-containing molecules catalyzed by gold. This critical review mainly puts its emphasis on the recent progress in the field of gold-catalyzed transformations of cyclopropyl-, cyclopropenyl-, epoxy-and aziridinyl-containing molecules. The rapid construction of interesting building blocks in organic synthesis from strained small rings catalyzed by gold has been summarized in this review (106 references).

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