Journal
CHEMICAL SOCIETY REVIEWS
Volume 40, Issue 9, Pages 4550-4562Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cs15069c
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Methods that furnish enantioenriched products are crucial in modern organic synthesis. An underutilized strategy to arrive at enantioenriched products is to perform divergent reactions on racemic mixtures, where each enantiomer of the starting material reacts with a single chiral reagent to furnish two separable, non-enantiomeric products that are enantioenriched. Stereodivergent, regiodivergent and structurally divergent reactions on racemic mixtures are discussed in this tutorial review.
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