Journal
CHEMICAL SOCIETY REVIEWS
Volume 39, Issue 8, Pages 2891-2902Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b821314n
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Funding
- MEC [CTQ2004-00808/BQU, CTQ2007-62771/BQU, CSD2007-00006]
- Generalitat Valenciana [GV/2007/142, PROMETEO/2009/039]
- University of Alicante
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Oxime-derived palladacycles are very efficient and versatile pre-catalysts for a wide range of carbon-carbon bond coupling reactions in air, under very low loading conditions, and employing reagent-grade chemicals. This tutorial review presents the main achievements, advantages and limitations of oxime palladacycles as a source of highly active palladium nanoparticles for high-turnover catalyzed Heck, as well as other homo-and cross-coupling reactions usually carried out employing organic or aqueous solvents. Comparison with other ligandless Pd(II) catalysts is also presented. Recent advances to develop supported oxime-derived palladacycles in order to facilitate precatalyst recovery and reuse in cross-coupling reactions, especially under aqueous reaction conditions, are also discussed.
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