Journal
CHEMICAL SOCIETY REVIEWS
Volume 38, Issue 12, Pages 3419-3434Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b901649j
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Funding
- National Science Foundation of China [20531020, 20721063, 20771028]
- Shanghai Leading Academic Discipline Project [B108]
- Shanghai Science and Technology Committee [08DZ2270500, 08DJ1400103]
- National Basic Research Program of China [2009CB825300]
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Over the past decade, supramolecular compounds with organometallic Ir, Rh, Ru based half-sandwich complexes have received considerable attention as materials with a variety of potential applications. The major emphasis of this tutorial review lies on the self-assembly of such organometallic half-sandwich molecular rectangles, prisms and cages with half-sandwich corners and two different rigid bifunctional ligands using an approach of stepwise construction. Synthetic methods and the structural and functional properties of the target complexes are discussed in detail.
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