4.8 Review

Spectroelectrochemistry: the best of two worlds

Journal

CHEMICAL SOCIETY REVIEWS
Volume 38, Issue 12, Pages 3373-3382

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b504286k

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Funding

  1. Deutsche Forschungsgemeinschaft (DFG)
  2. Fonds der Chemischen Industrie (FCI)
  3. COST Programme (Action D35) of the European Union
  4. Ministry of Education of the Czech Republic [COST OC 140]

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The combination of reaction-oriented electrochemistry with species-focussed spectroscopy in spectroelectrochemistry (SEC) allows for a more complete analysis of single and multiple electron-transfer processes and redox reactions in general. Practical considerations and guidelines are provided in this tutorial review, and selected examples involving UV-VIS-NIR and IR absorption spectroscopy as well as electron paramagnetic resonance (EPR) are presented to illustrate the potential and the applicability of this technique.

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