Journal
CHEMICAL SOCIETY REVIEWS
Volume 38, Issue 5, Pages 1315-1329Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b802258p
Keywords
-
Categories
Ask authors/readers for more resources
The modi. cation of metal-organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, 'click' chemistry, and other reactions are suitable for postsynthetic modi. cation (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available