4.8 Review

Two-dimensional chirality at liquid-solid interfaces

Journal

CHEMICAL SOCIETY REVIEWS
Volume 38, Issue 3, Pages 722-736

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b800403j

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Funding

  1. European Union Marie Curie Research Training Network CHEXTAN [MRTN-CT-2004-512161]
  2. Belgian Federal Science Policy Office [PAI 6/27]
  3. Fund of Scientific Research Flanders (FWO)
  4. Institute for the Promotion of Innovation by Science and Technology in Flanders (IWT)

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This tutorial review highlights the formation of chiral molecular patterns at the liquid-solid interface, revealed at the submolecular level with scanning tunnelling microscopy. It is shown that chiral patterns can be formed by both chiral and achiral molecules. The assembly of mixtures of mirror-image-like molecules gets special attention. Finally, non-standard methods to induce surface chirality in achiral systems are discussed.

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