Journal
CHEMICAL SOCIETY REVIEWS
Volume 37, Issue 6, Pages 1218-1228Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b718357g
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In marked contrast to Michael reactions, oxa-Michael reactions have not been used as standard transformations in organic synthesis until quite recently. This was mainly due to a lack of reactivity and selectivity, although the potential products of such reactions are valuable intermediates. This tutorial review presents recent major advances in the field of oxa-Michael (sometimes called oxo-Michael or oxy-Michael) reactions and applications in the total synthesis of complex natural products.
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