Journal
CHEMICAL SOCIETY REVIEWS
Volume 37, Issue 6, Pages 1264-1277Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b708843b
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This critical review highlights the ligand oriented catalyst design concept'', a new catalyst design concept for olefin polymerization that has led to the development of high-activity catalysts. The concept has created a series of highly active ethylene polymerization catalysts, many of which show high activities comparable to those of group 4 metallocene catalysts. Moreover, these catalysts display unique polymerization catalysis to produce a wide variety of polymers that possess unprecedented molecular architectures that are either difficult or impossible to achieve using conventional catalysts (98 references).
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