4.6 Article

Nickel, Cobalt and Palladium Catalysed C-H Functionalization of Un-Activated C(sp3)-H Bond

Journal

CHEMICAL RECORD
Volume 19, Issue 9, Pages 1829-1857

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201800093

Keywords

transition metal; un-activated gamma and beta C(sp(3))-H bond activations; auxiliary ligand; directing group; coupling reaction

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This review represents nickel, cobalt and palladium catalyzed C-H activation of sp(3) carbon, with special emphasis on methyl C-H activation. The importance of directing group assistance and effect of ligand on beta- or gamma- C(sp(3))-H activation is summarized in this review. The mechanistic study for Ni, Co and Pd catalyzed sp(3) C-H bond functionalization also discussed in detail.

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