Journal
CHEMICAL RECORD
Volume 14, Issue 2, Pages 280-302Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201300039
Keywords
asymmetric catalysis; cyclization; cycloaddition; gold; heterocycles
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Funding
- National Natural Science Foundation of China [21372084]
- 973 Program [2011CB808600]
- Fok Ying Tung Education Foundation [121014]
- Program of Eastern Scholar at Shanghai Institutions of Higher Learning
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This account describes our recent efforts devoted to gold chemistry since 2009. Based on furyl-Au 1,3-dipole analogues and related gold carbene intermediates, a rich variety of gold-catalyzed cascade reactions have been developed, which provide facile access to a diverse range of novel carbo- and heterocycles. In these reactions, the selectivity can be well controlled by the catalyst (ligand and metal), substrate or reagent. In addition, we have also developed the corresponding enantioselective variants, which are guided by bis(phosphinegold) complexes derived from axially chiral scaffolds and asymmetric gold/chiral Bronsted acid relay catalysis.
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