Journal
CHEMICAL RECORD
Volume 14, Issue 1, Pages 15-27Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201300014
Keywords
chirality; helical structures; noncovalent interactions; polyketides; self-assembly
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Funding
- Japan Society for the Promotion of Science (JSPS) [21229001, 23790003, 25860003]
- JSPS for a Fellowship for Young Japanese Scientists
- Grants-in-Aid for Scientific Research [12J09636, 25860003, 21229001] Funding Source: KAKEN
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Polycyclic aromatic compounds are an important group of substances in chemistry, and the study of their properties is a subject of interest in the development of drugs and materials. We have been conducting studies to develop chiral polycyclic aromatic compounds, i.e., helicenes and equatorenes. These helical molecules showed notable aggregate-forming properties and the capability for chiral recognition exerted by noncovalent bond interactions, which were not observed in compounds with central chirality. Homo- and hetero-double-helix-forming helicene oligomers were developed, and the latter self-assembled to form gels and vesicles. In this article, we describe such hierarchical studies of polycyclic aromatic compounds, which were started from polyketide aldol synthesis.
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