Journal
CHEMICAL RECORD
Volume 13, Issue 2, Pages 187-208Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201200028
Keywords
dimerization; electron transfer; radical reactions; reduction; samarium
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Funding
- Institut de Chimie Moleculaire et des Materiaux d'Orsay (Universite Paris-Sud)
- Institut de Chimie Moleculaire et des Materiaux d'Orsay (UMR CNRS) [8182]
- Department of Chemistry, Delhi University
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In the early eighties, we introduced samarium diiodide for the transformation of various functional groups. Since then, this reducing agent has been extensively used for the reductive cleavage of single bonds, C-C bond formations, C-N bond formations, and -elimination reactions. In this Personal Account, we highlight our initial results, as well as some of the contributions from various research groups. Because of space limitations, we arbitrarily select some useful results that have recently been described in literature.
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