Journal
CHEMICAL PHYSICS LETTERS
Volume 574, Issue -, Pages 13-17Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2013.05.009
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Funding
- Polish Ministry of Science and Higher Education [BMN/538-8371-B019-13, 530-8371-D191-12]
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The ability of ionizing water molecules by chosen strong oxidizing agents of superhalogen nature is demonstrated. It is shown that two selected Gutsev-Boldyrev superhalogens, BF4 and AlF4 (whose corresponding daughter anions BF4- and AlF4- are known to strongly bind an excess electron), might be employed to ionize single water molecule and small water clusters ((H2O), n = 2-4) which results in forming [(H2O)(n)](+)[BE4](-) and [(H2O)(n)](+)[AlF4](-) stable species (n = 1-4). The [(H2O)(n)](+)[BE4](-) and [(H2O)(n)](+)[AlF4](-) molecules are characterized by large values of binding (interaction) energy (28-73 kcal/mol) and substantial charge flow (0.5-0.8 au) between the components which confirms their ionic nature. (C) 2013 Elsevier B.V. All rights reserved.
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