Journal
CHEMICAL PHYSICS LETTERS
Volume 585, Issue -, Pages 198-200Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2013.09.004
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The fuzzy atoms formalism of analysing the wave function in terms of the three-dimensional (3D) space permits one to obtain effective atomic orbitals (3D variants of natural hybrids) from an SCF calculation. It is demonstrated here that a Hilbert-space analysis performed in the basis of these effective AO-s exactly reproduces the results of the fuzzy atoms 3D analysis: the Mulliken net and overlap populations calculated in that special basis coincide with the fuzzy atoms net and overlap populations, and the same holds for the bond orders calculated in that basis and in the fuzzy atoms framework. (C) 2013 Elsevier B.V. All rights reserved.
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