Journal
CHEMICAL PHYSICS LETTERS
Volume 535, Issue -, Pages 12-16Publisher
ELSEVIER
DOI: 10.1016/j.cplett.2012.03.051
Keywords
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Funding
- Grants-in-Aid for Scientific Research [23750012, 11F01029] Funding Source: KAKEN
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Photoelectron spectra of solvated electrons in bulk liquids were obtained at energy-resolution of 60 meV using a linear time-of-flight photoelectron spectrometer and a 100 kHz ultraviolet femtosecond laser. Solvated electrons in H2O, D2O, methanol, and ethanol were generated by 226 nm excitation of the charge-transfer-to-solvent bands of I in 0.1 M NaI solutions, and the photoelectron spectra were measured using 260 nm pulses with a time delay of 2 ns. The electron binding energies and band shapes are discussed. (C) 2012 Elsevier B. V. All rights reserved.
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