Journal
CHEMICAL PHYSICS LETTERS
Volume 521, Issue -, Pages 45-51Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2011.11.062
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Funding
- JST-CREST
- Japan Society for the Promotion of Science (JSPS)
- Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT)
- Grants-in-Aid for Scientific Research [23750029, 21350019] Funding Source: KAKEN
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We have theoretically investigated the correlation satellite spectra associated with the single-site (ss) and two-site (ts) double core-hole (DCH) states. The calculated ssDCH satellite spectra of N-2 (N 1s(2)) and CO (O 1s(2)) reproduced the observed experimental spectra satisfactorily and provided the first detailed assignments. DCH spectroscopy using X-ray two-photon photoelectron spectroscopy (XTPPS) was examined taking account of the single core-hole (SCH) and DCH satellite spectra. The results demonstrate that in XTPPS the ssDCH satellite spectrum is separated from other SCH/tsDCH spectra, while the tsDCH states and their satellite states may be overlapped with the SCH satellite spectrum. (C) 2011 Elsevier B. V. All rights reserved.
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