4.6 Article

H-bond switching and ligand exchange dynamics in aqueous ionic solution

Journal

CHEMICAL PHYSICS LETTERS
Volume 504, Issue 1-3, Pages 1-6

Publisher

ELSEVIER
DOI: 10.1016/j.cplett.2011.01.063

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Funding

  1. PULSE Institute at SLAC National Accelerator Laboratory by the US Department of Energy, Office of Basic Energy Sciences
  2. Swedish Research Council (VR)
  3. Carl Trygger foundation
  4. Magnus Bergvall foundation

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Aqueous ionic solutions lubricate the chemical machinery of the environment and life. Understanding the impact of ions on the properties of aqueous solutions and how these modified properties influence chemical and conformational dynamics remains an important and elusive objective of physical chemistry research. Here we discuss recent advances in our understanding that have been derived from ultrafast vibrational spectroscopy and molecular dynamics simulations. (C) 2011 Elsevier B. V. All rights reserved.

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