Journal
CHEMICAL PHYSICS LETTERS
Volume 495, Issue 4-6, Pages 222-227Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2010.06.087
Keywords
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Funding
- National Basic Research Program of China [2007CB815203]
- NSFC [20573097, 20803066, 20703038]
- NSFZ [R405465, Y409016]
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The A- and B-band resonance Raman spectra of Cu(II)-bisacetylacetone in methanol solution were obtained and their intensity patterns were found to be significantly different. It appears that the A- band structural dynamics is mostly along the photophysically and photochemically important C(gamma)C(beta)/C(beta)C(alpha) and Cu-O stretch reaction coordinates, while the B-band structural dynamics is mainly along photochemically important Cu-O stretch reaction coordinate. The significantly different structural dynamics provide an evident that the primary photoreduction reactions of Cu(II)-bisacetylacetone are wavelength dependence. (C) 2010 Elsevier B.V. All rights reserved.
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