4.6 Article

2D IR photon echo study of the anharmonic coupling in the OCN region of phenyl cyanate

Journal

CHEMICAL PHYSICS LETTERS
Volume 470, Issue 1-3, Pages 80-84

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2009.01.025

Keywords

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Funding

  1. NIH
  2. NSF and instrumentation developed at the Research Resource [NIH P41RR001348]
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [0809752] Funding Source: National Science Foundation

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The vibrations in the OCN stretching region of phenyl cyanate are examined by two-dimensional infrared spectroscopy. In water and THF, these spectra display three diagonal peaks having cross peaks characteristic of anharmonically coupled transitions. The pattern of the spectra is reproduced by coupling of two overtones with the OCN fundamental. (C) 2009 Elsevier B.V. All rights reserved.

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