Journal
CHEMICAL PHYSICS LETTERS
Volume 454, Issue 1-3, Pages 12-16Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2008.01.060
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We present new measurements of the perturber-induced shift of the CH3I ionization energy at low perturber number densities and analyze these data within the local Wigner-Seitz model previously used at high density. We compare the local Wigner-Seitz model with the scattering approach developed by Fermi, and modified by Alekseev and Sobel'man, and show that the local Wigner-Seitz model extends smoothly into the low density region and accurately predicts the temperature dependence of the shift in ionization energy. Published by Elsevier B. V.
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