Journal
CHEMICAL PHYSICS LETTERS
Volume 465, Issue 4-6, Pages 230-233Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2008.10.002
Keywords
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Funding
- NSFC
- Chinese Academy of Sciences
- State Key Basic Research Program
- National Science Fund for Distinguished Young Scholars
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Triad 1 consisting of TTF, maleimide and pyrene units acts as a temperature-regulated molecular redox fluorescence switch by combining features of the three moieties. Our results show that the fluorescence modulation by redox reaction of TTF unit in triad 1 is controlled by the 'status' of the maleimide unit which is involved in the reversible temperature-dependent Diels-Alder reaction with furan. Thus, a reset-table temperature-regulated molecular redox fluorescence switch is successfully realized with triad 1. (C) 2008 Elsevier B.V. All rights reserved.
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