Journal
CHEMICAL PHYSICS LETTERS
Volume 450, Issue 4-6, Pages 426-430Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2007.11.064
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It is shown how the presence of a chiral compound in solution induces chirality in the surrounding solvent molecules. Using Vibrational Circular Dichroism on camphor dissolved in deuterated chloroform, it is found that the C-D stretch in the latter indeed becomes VCD active. The experimental results agree with ab initio computed spectra for 1:1 associations between the solvent and solute. (c) 2007 Elsevier B.V. All rights reserved.
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