Journal
CHEMICAL PHYSICS
Volume 402, Issue -, Pages 14-21Publisher
ELSEVIER
DOI: 10.1016/j.chemphys.2012.03.020
Keywords
Propyne; Overtones and combination bands; High resolution infrared spectrum; Supersonic expansion; Cavity ring down spectroscopy
Funding
- Universita di Bologna
- Ministero della Ricerca e dell'Universita
- Action de Recherches Concertees de la Communaute francaise de Belgique
- F.R.S.-FNRS
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The absorption spectrum of propyne (CH3CCH) has been investigated in the range 6200-6700 cm (1). Data were obtained using three different experimental techniques: conventional FTIR experiments (room temperature, 0.018 cm (1) resolution, 10 m absorption path), FTIR experiments using a femtosecond broadband absorption source and a build up cavity (room temperature, 0.02 cm (1) resolution, absorption path between 1500 and 12,000 m), cavity ring down spectroscopy to probe a propyne/Ar supersonic expansion (T-rot approximate to 20 K, sub-Doppler resolution, 720 m effective absorption path length). The analysis focused on one perpendicular (nu(1) + nu(+/- 1)(6)) and four parallel (2 nu(1), nu(1) + nu(2), nu(1) + nu(3) + nu(5), nu(1) + nu(3) + 2 nu(0)(9)) bands, all perturbed by a complex system of Coriolis and anharmonic interactions. A model Hamiltonian was built, including all symmetry allowed perturbations between the upper levels of the studied bands but not accounting for additional interacting states. In total 1176 rovibrational transitions have been assigned and simultaneously fitted (sigma = 0.0029 cm (1)), leading to a set of effective rovibrational parameters. The resulting polyad structure is discussed and additional bands identified in the spectral range are tentatively assigned. (C) 2012 Elsevier B. V. All rights reserved.
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