Journal
CHEMICAL ENGINEERING SCIENCE
Volume 102, Issue -, Pages 373-377Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2013.08.032
Keywords
Quinolinium; Ionic liquid; Dibenzothiophene; COSMO-RS; Partition coefficient; Extraction
Categories
Funding
- Universiti Teknologi PETRONAS
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A range of ionic liquids (ILS) with different cation and anion had been investigated for its ability to extract dibenzothiophene (DBT) from n-dodecane through COSMO-RS prediction and experiment. COSMO-RS showed quinolinium-based ILs as one of the potential ILs for hydrocarbon desulfurization. In real experiment, 1-butyl-6-methylquinolinium thiocyanate and 1-butyl-6-methylquinoliniumdicyanamide were synthesized and have shown to have the highest desulfurization efficiency in model oil among the ILs investigated. (C) 2013 Elsevier Ltd. All rights reserved.
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