4.7 Article

PANI/GO as a super adsorbent for the selective adsorption of uranium(VI)

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 255, Issue -, Pages 604-612

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2014.06.063

Keywords

Uranium; Graphene oxide; Polyaniline; Selective adsorption

Funding

  1. National Natural Science Foundation of China [21207136, 21225730, 21307135, 21377132]
  2. Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences [DSJJ-13-YY01]

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In this paper, polyaniline modified graphene oxide (PANI/GO) composites were synthesized by in situ polymerization technique, and applied to preconcentrate U(VI) from aqueous solutions. The PANI/GO composites have exceptionally capability in selective extraction of U(VI) from aqueous solution under a variety of conditions. The maximum adsorption capacities of PANI/GO composites for U(VI) achieve to 1960 mg/g at pH 5.0 and 610 mg/g at pH 3.5, which are two orders of magnitude higher than those of traditional adsorbents and today's nanomaterials. PANI/GO composites also present ideal tolerance to high salt concentrations and excellent regeneration-reuse property. Thereby, PANI/GO composites have exceptional potential applications in the extraction of U(VI) from aqueous solution in nuclear fuel achievement and for U(VI) environmental pollution cleanup. Published by Elsevier B.V.

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