Journal
CHEMICAL ENGINEERING JOURNAL
Volume 232, Issue -, Pages 582-590Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.08.011
Keywords
Activated carbon; High surface area; Acid scarlet; Adsorption mechanism
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Funding
- Doctoral Program of Higher Education of China [2010013111 0005]
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Enteromorpha prolifera based-activated carbons were prepared using chemical activation by H4P2O7 (PAC) and KOH (KAC) and applied as a potential adsorbent for the adsorption of acid scarlet (GR). N-2 adsorption-desorption isotherms, scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and Boehm titration were used to compare the porous structure, surface chemical property and adsorption behavior of carbon. KAC presented higher surface area (3500 m(2)/g) and larger total pore volume (2.872 cm(3)/g). To account for the adsorption mechanisms, the kinetic models, including pseudo-first-order model, pseudo-second-order model, intraparticle diffusion model and Boyd model were introduced. The Langmuir isotherm model was better fitted with the equilibrium data than Freundlich and Dubinin-Radushkevich models. The maximum adsorption capacities of GR onto KAC and PAC were 2500 mg/g and 454 mg/g, respectively. The physical adsorption and ion-exchange were the dominating adsorption mechanism. (C) 2013 Elsevier B.V. All rights reserved.
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