Journal
CHEMICAL ENGINEERING JOURNAL
Volume 230, Issue -, Pages 456-465Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.06.118
Keywords
CO2 capture; Adsorption; Biomass; Carbon materials
Categories
Funding
- Spanish MINECO [ENE2011-23467]
- European Regional Development Fund (ERDF)
- CSIC (JAE-Doc program)
- MINECO (FPI program)
- European Social Fund
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Sustainable carbon adsorbents have been produced from biomass residues by single-step activation with CO2. The activation conditions were optimised to develop narrow micropores in order to maximise the CO2 adsorption capacity of the carbons under post-combustion conditions. The equilibrium of adsorption of pure CO2 and N-2 was measured between 0 degrees C and 50 degrees C up to 120 kPa for the outstanding carbons. The CO2 adsorption capacity measured at low pressures is among the highest ever reported for carbon materials (0.6-1.1 mmol g(-1) at 15 kPa and 25-50 degrees C), and the average isosteric heat of adsorption is typical of a physisorption process: 27 kJ mol(-1). Dynamic experiments carried out in a fixed-bed adsorption unit showed fast adsorption and desorption kinetics and a high CO2-over-N-2 selectivity. These adsorbents are able to separate a mixture with 14% CO2 (balance N-2) at 50 degrees C, conditions that can be considered as representative of post-combustion conditions, and they can be easily regenerated. (c) 2013 Elsevier B.V. All rights reserved.
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