4.7 Article

CuFe2O4 magnetic nanoparticles: A simple and efficient catalyst for the reduction of nitrophenol

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 221, Issue -, Pages 16-24

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.02.009

Keywords

CuFe2O4 magnetic nanoparticles; 4-Nitrophenol; Catalytic reduction; Pseudo-first-order reaction

Funding

  1. National Natural Science Foundation of China [210750565, 21207057]
  2. National Fund for Talent Training in Basic Science of China [J1103307]

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In this paper, we discovered that CuFe2O4 magnetic nanoparticles (MNPs) possessed high catalytic performance in the reduction of nitrophenol for the first time. The as-prepared CuFe2O4 MNPs exhibited several advantages such as stability, monodispersity, low-cost, simplicity and rapid separation performance over other catalysts for the reduction of nitrophenol. The CuFe2O4 MNPs showed high efficiency in the catalytic reduction of 4-nitrophenol to 4-aminophenol with the conversion of 95% within 40s in the presence of NaBH4. The pseudo-first-order kinetic equation could describe the reduction of 4-nitrophenol with the excess amount of NaBH4. (C) 2013 Elsevier B.V. All rights reserved.

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